Plutonium (Pu)

Science / Periodic Table of Elements / Plutonium (Pu): Atomic number: 94, Atomic mass: (244) g.mol -1, Electronegativity: unknown, Density: 19.84 g.cm-3 at 20°C, Melting point: 641 °C, Boiling point: 3232 °C, Vanderwaals radius: unknown, Ionic radius: unknown, Isotopes: 11, Electronic shell: [ Rn ] 5f6 7s2, Energy of first ionisation: 558.6 kJ.mol -1, Discovered by: G.T. Seaborg in 1940. Plutonium was discovered in 1941 by Dr. Glenn T. Seaborg and Edwin McMillan, Kennedy, and Wahl by deuteron bombardment of uranium in the 60-inch cyclotron of the Berkeley Radiation Laboratory at the University of California, Berkeley, but the discovery was kept secret. It was named after the planet Pluto, having been discovered directly after Neptunium. (Pluto is the next planet out after Neptune). The metal has a silvery appearance and takes on a yellow tarnish when slightly oxidized. It is chemically reactive. A relatively large piece of plutonium is warm to the touch because of the energy given off in alpha decay. Larger pieces will produce enough heat to boil water. The metal readily dissolves in concentrated hydrochloric acid, hydroiodic acid, or perchloric acid. The metal exhibits six allotropic modifications having various crystalline structures. The densities of these vary from 16.00 to 19.86 g/cm3. The most important isotope of plutonium is 239Pu, with a half-life of 24,200 years. Because of its short half-life, there are only extremely tiny trace amounts of plutonium naturally in uranium ores. It is produced in extensive quantities in nuclear reactors from natural uranium: 238U(n, gamma) --> 239U--(beta) --> 239Np--(beta) --> 239Pu. Fifteen isotopes of plutonium are known. Applications: Plutonium is a key fissile component in modern nuclear weapons; care must be taken to avoid accumulation of amounts of plutonium which approach critical mass, the amount of plutonium which will self-generate a nuclear reaction. Despite not being confined by external pressure as is required for a nuclear weapon, it will nevertheless heat itself and break whatever confining environment it is in. Shape is relevant; compact shapes such as spheres are to be avoided. Plutonium could also be used to manufacture radiological weapons. The plutonium isotope 238Pu is an alpha emitter with a half life of 87 years. These characteristics make it well suited for electrical power generation for devices which must function without direct maintenance for timescales approximating a human life time. It is therefore used in RTGs such as those powering the Galileo and Cassini space probes. Plutonium-238 was used on the Apollo-14 lunar flight in 1971 to power seismic devices and other equipment left on the Moon, and it was also the power supply of the two Voyager supercraft launched in 1977. Plutonium-239 can also be used as a fuel in a new generation of fast-breeder nuclear weapons, which burn a mixed oxide (MOX) fuel consisting of uranium and plutonium. Plutonium in the environment: Trace amounts of plutonium are found naturally in uranium-rich ores. Humans produce most of the existing plutonium, in special nuclear reactors. Besides being naturally present in very small amounts, plutonium may also enter the environment from releases of nuclear reactors, weapons production plants, and research facilities. A major source of plutonium release is nuclear weapons testing. Annual world production of plutonium is probably in excess of 50 tonnes and there may be more than 1.000 tonnes of metal in storage, either as bombs or as metal rods.

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